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國(guó)外名校名著--化工過(guò)程分析、綜合與設(shè)計(jì) 第五版(英文原版影印) 讀者對(duì)象:《化工過(guò)程分析、綜合與設(shè)計(jì)》可作為高等學(xué)校化工及相關(guān)專業(yè)本科生的教材和畢業(yè)設(shè)計(jì)指導(dǎo)參考書(shū),也可供石油與化工、制藥及輕工等行業(yè)從事科研開(kāi)發(fā)、生產(chǎn)技術(shù)管理和工程設(shè)計(jì)的人員及研究生參考。
《化工過(guò)程分析、綜合與設(shè)計(jì)》是Richard Turton、Joseph A. Shaeiwitz、Debangsu Bhattacharyya和Wallace B. Whiting教授所著的國(guó)際經(jīng)典教材。本書(shū)是原著第五版的影印版,從化工設(shè)計(jì)所需的基礎(chǔ)知識(shí)講起,指導(dǎo)完整設(shè)計(jì)一個(gè)化工流程,每篇分別講述了設(shè)計(jì)過(guò)程所涉及的方方面面,包括化工過(guò)程的概念與分析、工程經(jīng)濟(jì)分析、合成與優(yōu)化,化工設(shè)備和工藝設(shè)備的設(shè)計(jì)與性能,化工設(shè)計(jì)對(duì)社會(huì)的影響,以及人際關(guān)系和溝通技巧。本書(shū)包括最新的安全和倫理資源,并重點(diǎn)介紹了常見(jiàn)單元操作的設(shè)備設(shè)計(jì),如流體流動(dòng)、傳熱、分離、反應(yīng)器等。以15種化工工藝和6個(gè)工程項(xiàng)目為例,論述了化工設(shè)計(jì)常用方法,重點(diǎn)解釋了設(shè)計(jì)思路。
《化工過(guò)程分析、綜合與設(shè)計(jì)》可作為高等學(xué);ぜ跋嚓P(guān)專業(yè)本科生的教材和畢業(yè)設(shè)計(jì)指導(dǎo)參考書(shū),也可供石油與化工、制藥及輕工等行業(yè)從事科研開(kāi)發(fā)、生產(chǎn)技術(shù)管理和工程設(shè)計(jì)的人員及研究生參考。
理查德·特頓(Richard Turton)在過(guò)去的32年里,一直在西弗吉尼亞大學(xué)教授設(shè)計(jì)及相關(guān)課程。在此之前,他在設(shè)計(jì)和建筑行業(yè)工作了5年。他的主要研究方向是設(shè)計(jì)和過(guò)程系統(tǒng)建模。
約瑟夫·A. 謝維茨(Joseph A. Shaeiwitz)在西弗吉尼亞大學(xué)教授設(shè)計(jì)及相關(guān)課程超過(guò)25年。他現(xiàn)在在奧本大學(xué)教授設(shè)計(jì)課程。他的研究方向包括過(guò)程設(shè)計(jì)和成果評(píng)估。 德邦蘇·巴塔查里亞(Debangsu Bhattacharyya)擁有十余年大型煉油廠的工作經(jīng)驗(yàn)。在煉油廠工作期間,他從事工藝操作、裝置開(kāi)車、大規(guī)模工藝模擬和過(guò)程控制工作。他的主要研究方向是過(guò)程建模、動(dòng)態(tài)仿真、狀態(tài)估計(jì)、傳感器配置和高級(jí)過(guò)程控制。 華萊士·B. 懷廷(Wallace B. Whiting)是內(nèi)華達(dá)大學(xué)里諾分校的名譽(yù)教授,從事化工工藝設(shè)計(jì)的實(shí)踐和教學(xué)工作超過(guò)24年。
Nomenclature
符號(hào)表 第0章 Outcomes Assessment 成果評(píng)估 1 0.1 Student Self-Assessment / 學(xué)生自我評(píng)估 / 2 0.2 Assessment by Faculty / 教員評(píng)估 / 4 0.3 Summary / 總結(jié) / 6 References / 參考文獻(xiàn) / 6 第1篇 Conceptualization and Analysis of Chemical Processes 化工過(guò)程的概念與分析 7 第1章 Diagrams for Understanding Chemical Processes 了解化工過(guò)程的圖表 9 1.1 Block Flow Diagram (BFD) / 程序框圖(BFD)/ 11 1.1.1 Block Flow Process Diagram / 方框流程圖 / 11 1.1.2 Block Flow Plant Diagram / 方塊流程工廠圖 / 12 1.2 Process Flow Diagram (PFD) / 工藝流程圖(PFD)/ 14 1.2.1 Process Topology / 流程拓?fù)?/ 14 1.2.2 Stream Information / 物流數(shù)據(jù) / 18 1.2.3 Equipment Information / 設(shè)備信息 / 21 1.2.4 Combining Topology, Stream Data, and Control Strategy to Give a PFD / 結(jié)合拓?fù)洹⑽锪鲾?shù)據(jù)和控制策略的PFD圖 / 21 1.3 Piping and Instrumentation Diagram (P&ID) / 管道及儀表流程圖(P&ID)/ 27 1.4 Additional Diagrams / 附加圖表 / 32 1.5 Three-Dimensional Representation of a Process / 過(guò)程的三維表示 / 34 1.6 The 3-D Plant Model / 三維工廠模型 / 41 1.7 Operator and 3-D Immersive Training Simulators / 操作員及3-D沉浸式訓(xùn)練仿真器 / 43 1.7.1 Operator Training Simulators (OTS) / 操作員訓(xùn)練仿真器(OTS)/ 43 1.7.2 3-D Immersive Training Simulators (ITS) / 三維沉浸式訓(xùn)練仿真器(ITS)/ 45 1.7.3 Linking the ITS with an OTS / 連接ITS和OTS / 46 1.8 Summary / 總結(jié) / 48 References / 參考文獻(xiàn) / 49 Short Answer Questions / 簡(jiǎn)答題 / 49 Problems / 習(xí)題 / 50 第2章 The Structure and Synthesis of Process Flow Diagrams 工藝流程圖的結(jié)構(gòu)與綜合 55 2.1 Hierarchy of Process Design / 過(guò)程設(shè)計(jì)的層次結(jié)構(gòu) / 55 2.2 Step 1—Batch versus Continuous Process / 步驟1——間歇過(guò)程與連續(xù)過(guò)程 / 56 2.3 Step 2—The Input/Output Structure of the Process / 步驟2——過(guò)程的輸入/輸出結(jié)構(gòu) / 60 2.3.1 Process Concept Diagram / 過(guò)程概念圖 / 60 2.3.2 The Input/Output Structure of the Process Flow Diagram / 工藝流程圖的輸入/輸出結(jié)構(gòu) / 61 2.3.3 The Input/Output Structure and Other Features of the Generic Block Flow Process Diagram / 通用方框流程圖的輸入/輸出結(jié)構(gòu)及其他特征 / 63 2.3.4 Other Considerations for the Input/Output Structure of the Process Flowsheet / 工藝流程圖輸入/輸出結(jié)構(gòu)的其他考慮因素 / 65 2.3.5 What Information Can Be Determined Using the Input/Output Diagram for a Process? / 使用過(guò)程的輸入/輸出圖可以確定哪些信息 / 68 2.4 Step 3—The Recycle Structure of the Process / 第三步——過(guò)程的循環(huán)結(jié)構(gòu) / 70 2.4.1 Efficiency of Raw Material Usage / 原材料使用效率 / 70 2.4.2 Identification and Definition of the Recycle Structure of the Process / 工藝循環(huán)結(jié)構(gòu)的識(shí)別和定義 / 71 2.4.3 Other Issues Affecting the Recycle Structure That Lead to Process Alternatives / 影響導(dǎo)致工藝替代的循環(huán)結(jié)構(gòu)的其他問(wèn)題 / 75 2.5 Step 4—General Structure of the Separation System / 第4步——分離系統(tǒng)的一般結(jié)構(gòu) / 83 2.6 Step 5—Heat-Exchanger Network or Process Energy Recovery System / 第5步——換熱網(wǎng)絡(luò)或過(guò)程能量回收系統(tǒng) / 83 2.7 Information Required and Sources / 所需信息和來(lái)源 / 83 2.8 Summary / 總結(jié) / 83 References / 參考文獻(xiàn) / 85 Short Answer Questions / 簡(jiǎn)答題 / 86 Problems / 習(xí)題 / 86 第3章 Batch Processing 間歇過(guò)程 91 3.1 Design Calculations for Batch Processes / 間歇過(guò)程的設(shè)計(jì)計(jì)算 / 91 3.2 Gantt Charts and Scheduling / 甘特圖和進(jìn)度計(jì)劃 / 97 3.3 Nonoverlapping Operations, Overlapping Operations, and Cycle Times / 非重疊操作、重疊操作和周期時(shí)間 / 98 3.4 Flowshop and Jobshop Plants / 流水線和車間工廠 / 101 3.4.1 Flowshop Plants / 流水線工廠 / 101 3.4.2 Jobshop Plants / 車間工廠 / 103 3.5 Product and Intermediate Storage and Parallel Process Units / 產(chǎn)品和中間存儲(chǔ)及并行處理單元 / 106 3.5.1 Product Storage for Single-Product Campaigns / 單一產(chǎn)品活動(dòng)的產(chǎn)品存儲(chǔ) / 106 3.5.2 Intermediate Storage / 中間存儲(chǔ) / 108 3.5.3 Parallel Process Units / 并行處理單元 / 110 3.6 Design of Equipment for Multiproduct Batch Processes / 多產(chǎn)品間歇處理設(shè)備的設(shè)計(jì) / 111 3.7 Summary / 總結(jié) / 113 References / 參考文獻(xiàn) / 114 Short Answer Questions / 簡(jiǎn)答題 / 114 Problems / 習(xí)題 / 114 第4章 Chemical Product Design 化工產(chǎn)品設(shè)計(jì) 123 4.1 Strategies for Chemical Product Design / 化工產(chǎn)品設(shè)計(jì)策略 / 124 4.2 Needs / 需求 / 125 4.3 Ideas / 方法 / 127 4.4 Selection / 篩選 / 128 4.5 Manufacture / 加工 / 130 4.6 Batch Processing / 間歇過(guò)程 / 131 4.7 Economic Considerations / 經(jīng)濟(jì)因素 / 131 4.8 Summary / 總結(jié) / 132 References / 參考文獻(xiàn) / 132 第5章 Tracing Chemicals through the Process Flow Diagram / 通過(guò)工藝流程圖追蹤化學(xué)品 135 5.1 Guidelines and Tactics for Tracing Chemicals / 追蹤化學(xué)品的指南和策略 / 135 5.2 Tracing Primary Paths Taken by Chemicals in a Chemical Process / 追蹤化學(xué)品在化學(xué)過(guò)程中的主要路徑 / 136 5.3 Recycle and Bypass Streams / 循環(huán)和旁通流 / 142 5.4 Tracing Nonreacting Chemicals / 追蹤不反應(yīng)的化學(xué)品 / 145 5.5 Limitations / 局限性 / 145 5.6 Written Process Description / 書(shū)面流程概況 / 146 5.7 Summary / 總結(jié) / 147 Problems / 習(xí)題 / 147 第6章 Understanding Process Conditions 了解工藝條件 149 6.1 Conditions of Special Concern for the Operation of Separation and Reactor Systems / 分離和反應(yīng)器系統(tǒng)運(yùn)行的特別關(guān)注條件 / 150 6.1.1 Pressure / 壓力 / 150 6.1.2 Temperature / 溫度 / 150 6.2 Reasons for Operating at Conditions of Special Concern / 在特別關(guān)注條件下操作的原因 / 152 6.3 Conditions of Special Concern for the Operation of Other Equipment / 其他設(shè)備運(yùn)行需要特別關(guān)注的條件 / 155 6.4 Analysis of Important Process Conditions / 關(guān)鍵工藝條件分析 / 158 6.4.1 Evaluation of Reactor R-101 / 反應(yīng)器R-101的評(píng)估 / 158 6.4.2 Evaluation of High-Pressure Phase Separator V-102 / 高壓相分離器V-102的評(píng)估 / 164 6.4.3 Evaluation of Large Temperature Driving Force in Exchanger E-101 / 換熱器E-101中高溫驅(qū)動(dòng)力的評(píng)估 / 164 6.4.4 Evaluation of Exchanger E-102 / 換熱器E-102的評(píng)估 / 164 6.4.5 Pressure Control Valve on Stream 8 / 流路8上的壓力控制閥 / 164 6.4.6 Pressure Control Valve on Stream from V-102 to V-103 / V-102至V-103流路上的壓力控制閥 / 164 6.5 Summary / 總結(jié) / 165 References / 參考文獻(xiàn) / 165 Short Answer Questions / 簡(jiǎn)答題 / 165 Problems / 習(xí)題 / 166 第2篇 Engineering Economic Analysis of Chemical Processes 化工過(guò)程的工程經(jīng)濟(jì)分析 169 第7章 Estimation of Capital Costs 固定成本估算 171 7.1 Classifications of Capital Cost Estimates / 固定成本估算的分類 / 172 7.2 Estimation of Purchased Equipment Costs / 采購(gòu)設(shè)備成本估算 / 175 7.2.1 Effect of Capacity on Purchased Equipment Cost / 產(chǎn)能對(duì)采購(gòu)設(shè)備成本的影響 / 175 7.2.2 Effect of Time on Purchased Equipment Cost / 時(shí)間對(duì)采購(gòu)設(shè)備成本的影響 / 179 7.3 Estimating the Total Capital Cost of a Plant / 估算工廠的總固定成本 / 182 7.3.1 Lang Factor Technique / 朗因子技術(shù) / 184 7.3.2 Module Costing Technique / 模塊成本技術(shù) / 185 7.3.3 Bare Module Cost for Equipment at Base Conditions / 基本條件下設(shè)備的裸模塊成本 / 186 7.3.4 Bare Module Cost for Non-Base-Case Conditions / 非基本條件下的裸模塊成本 / 189 7.3.5 Combination of Pressure and MOC Information to Give the Bare Module Factor, FBM, and Bare Module Cost, CBM / 結(jié)合壓力和MOC信息得出裸模塊系數(shù)(FBM)和裸模塊成本(CBM)/ 199 7.3.6 Algorithm for Calculating Bare Module Costs / 計(jì)算裸模塊成本的算法 / 200 7.3.7 Grassroots (Green Field) and Total Module Costs / 基層(綠地)和總模塊成本 / 201 7.3.8 A Computer Program (CAPCOST) for Capital Cost Estimation Using the Equipment Module Approach / 用設(shè)備模塊法進(jìn)行固定成本估算的計(jì)算機(jī)程序(CAPCOST)/ 204 7.4 Estimation of Plant Costs Based on Capacity Information / 基于產(chǎn)能信息的工廠成本估算 / 206 7.5 Summary / 總結(jié) / 208 References / 參考文獻(xiàn) / 208 Short Answer Questions / 簡(jiǎn)答題 / 209 Problems / 習(xí)題 / 210 第8章 Estimation of Manufacturing Costs 生產(chǎn)成本的估算 213 8.1 Factors Affecting the Cost of Manufacturing a Chemical Product / 影響化工產(chǎn)品生產(chǎn)成本的因素 / 213 8.2 Cost of Operating Labor / 運(yùn)營(yíng)人工成本 / 218 8.3 Utility Costs / 公用設(shè)施成本 / 219 8.3.1 Background Information on Utilities / 公用設(shè)施的背景信息 / 219 8.3.2 Calculation of Utility Costs / 公用設(shè)施成本計(jì)算 / 221 8.4 Raw Material Costs / 原材料成本 / 234 8.5 Yearly Costs and Stream Factors / 年度成本和生產(chǎn)定額 / 237 8.6 Estimating Utility Costs from the PFD / 根據(jù)PFD估算公用設(shè)施成本 / 238 8.7 Cost of Treating Liquid and Solid Waste Streams / 處理液體和固體廢物流的成本 / 240 8.8 Evaluation of Cost of Manufacture for the Production of Benzene via the Hydrodealkylation of Toluene / 甲苯加氫脫烷基制苯的生產(chǎn)成本估算 / 241 8.9 Summary / 總結(jié) / 242 References / 參考文獻(xiàn) / 243 Short Answer Questions / 簡(jiǎn)答題 / 243 Problems / 習(xí)題 / 244 第9章 Engineering Economic Analysis 工程經(jīng)濟(jì)分析 247 9.1 Investments and the Time Value of Money / 投資與貨幣的時(shí)間價(jià)值 / 248 9.2 Different Types of Interest / 不同類型的利率 / 251 9.2.1 Simple Interest / 單利 / 252 9.2.2 Compound Interest / 復(fù)利 / 252 9.2.3 Interest Rates Changing with Time / 利率隨時(shí)間的變化 / 253 9.3 Time Basis for Compound Interest Calculations / 復(fù)利計(jì)算的時(shí)間基準(zhǔn) / 254 9.3.1 Effective Annual Interest Rate / 實(shí)際年利率 / 254 9.3.2 Continuously Compounded Interest / 連續(xù)復(fù)利 / 255 9.4 Cash Flow Diagrams / 現(xiàn)金流通圖 / 255 9.4.1 Discrete Cash Flow Diagram / 離散現(xiàn)金流通圖 / 256 9.4.2 Cumulative Cash Flow Diagram / 累積現(xiàn)金流通圖 / 258 9.5 Calculations from Cash Flow Diagrams / 現(xiàn)金流通圖計(jì)算 / 259 9.5.1 Annuities—A Uniform Series of Cash Transactions / 年金——統(tǒng)一的現(xiàn)金交易系列 / 260 9.5.2 Discount Factors / 折現(xiàn)系數(shù) / 261 9.6 Inflation / 通貨膨脹 / 266 9.7 Depreciation of Capital Investment / 資本投資折舊 / 268 9.7.1 Fixed Capital, Working Capital, and Land / 固定資本、營(yíng)運(yùn)資本和土地 / 269 9.7.2 Different Types of Depreciation / 不同類型的折舊 / 269 9.7.3 Current Depreciation Method (2017): Modified Accelerated Cost Recovery System (MACRS) / 現(xiàn)行折舊方法(2017年):修正的加速成本回收系統(tǒng)(MACRS)/ 273 9.8 Taxation, Cash Flow, and Profit / 稅收、現(xiàn)金流和利潤(rùn) / 274 9.9 Summary / 總結(jié) / 277 References / 參考文獻(xiàn) / 277 Short Answer Questions / 簡(jiǎn)答題 / 278 Problems / 習(xí)題 / 278 第10章 Profitability Analysis 盈利能力分析 285 10.1 A Typical Cash Flow Diagram for a New Project / 新項(xiàng)目的典型現(xiàn)金流通圖 / 285 10.2 Profitability Criteria for Project Evaluation / 評(píng)估項(xiàng)目的盈利標(biāo)準(zhǔn) / 287 10.2.1 Nondiscounted Profitability Criteria / 無(wú)折現(xiàn)盈利標(biāo)準(zhǔn) / 287 10.2.2 Discounted Profitability Criteria / 折現(xiàn)盈利標(biāo)準(zhǔn) / 291 10.3 Comparing Several Large Projects: Incremental Economic Analysis / 比較幾個(gè)大型項(xiàng)目:增量經(jīng)濟(jì)分析 / 295 10.4 Establishing Acceptable Returns from Investments: The Concept of Risk / 建立可接受的投資回報(bào):風(fēng)險(xiǎn)概念 / 298 10.5 Evaluation of Equipment Alternatives / 設(shè)備替代品評(píng)估 / 299 10.5.1 Equipment with the Same Expected Operating Lives / 具有相同預(yù)期使用壽命的設(shè)備 / 299 10.5.2 Equipment with Different Expected Operating Lives / 具有不同預(yù)期使用壽命的設(shè)備 / 300 10.6 Incremental Analysis for Retrofitting Facilities / 改造設(shè)施的增量分析 / 305 10.6.1 Nondiscounted Methods for Incremental Analysis / 增量分析的無(wú)折現(xiàn)方法 / 305 10.6.2 Discounted Methods for Incremental Analysis / 增量分析的折現(xiàn)方法 / 308 10.7 Evaluation of Risk in Evaluating Profitability / 評(píng)估盈利能力時(shí)的風(fēng)險(xiǎn)評(píng)估 / 309 10.7.1 Forecasting Uncertainty in Chemical Processes / 化工過(guò)程的不確定性預(yù)測(cè) / 310 10.7.2 Quantifying Risk / 量化風(fēng)險(xiǎn) / 314 10.8 Profit Margin Analysis / 利潤(rùn)率分析 / 325 10.9 Summary / 總結(jié) / 326 References / 參考文獻(xiàn) / 327 Short Answer Questions / 簡(jiǎn)答題 / 327 Problems / 習(xí)題 / 328 第3篇 Synthesis and Optimization of Chemical Processes 化工過(guò)程的合成與優(yōu)化 343 第11章 Utilizing Experience-Based Principles to Confirm the Suitability of a Process Design 利用基于經(jīng)驗(yàn)的原則來(lái)確認(rèn)過(guò)程設(shè)計(jì)的適用性 347 11.1 The Role of Experience in the Design Process / 設(shè)計(jì)過(guò)程中經(jīng)驗(yàn)的作用 / 348 11.1.1 Introduction to Technical Heuristics and Shortcut Methods / 技術(shù)探索法和簡(jiǎn)捷法簡(jiǎn)介 / 348 11.1.2 Maximizing the Benefits Obtained from Experience / 從經(jīng)驗(yàn)中獲得最大化利益 / 349 11.2 Presentation of Tables of Technical Heuristics and Guidelines / 技術(shù)探索法和指南表格 / 351 11.3 Summary / 總結(jié) / 354 List of Informational Tables / 信息表 / 354 References / 參考文獻(xiàn) / 368 Problems / 習(xí)題 / 368 第12章 Synthesis of the PFD from the Generic BFD 從通用BFD合成PFD 369 12.1 Information Needs and Sources / 信息需求和來(lái)源 / 370 12.1.1 Interactions with Other Engineers and Scientists / 與其他工程師和科學(xué)家交流 / 370 12.1.2 Reaction Kinetics Data / 反應(yīng)動(dòng)力學(xué)數(shù)據(jù) / 370 12.1.3 Physical Property Data / 物性數(shù)據(jù) / 371 12.2 Reactor Section / 反應(yīng)器部分 / 372 12.3 Separator Section / 分離器部分 / 373 12.3.1 General Guidelines for Choosing Separation Operations / 選擇分離操作的一般準(zhǔn)則 / 374 12.3.2 Sequencing of Distillation Columns for Simple Distillation / 簡(jiǎn)單蒸餾的蒸餾塔排序 / 376 12.3.3 Azeotropic Distillation / 共沸蒸餾 / 378 12.4 Reactor Feed Preparation and Separator Feed Preparation Sections / 反應(yīng)器進(jìn)料和分離器進(jìn)料部分 / 388 12.5 Recycle Section / 再循環(huán)部分 / 389 12.6 Environmental Control Section / 環(huán)境控制組 / 389 12.7 Major Process Control Loops / 主要過(guò)程控制回路 / 390 12.8 Flow Summary Table / 流量匯總表 / 390 12.9 Major Equipment Summary Table / 主要設(shè)備匯總表 / 390 12.10 Summary / 總結(jié) / 391 References / 參考文獻(xiàn) / 391 Problems / 習(xí)題 / 392 第13章 Synthesis of a Process Using a Simulator and Simulator Troubleshooting 使用模擬器進(jìn)行過(guò)程合成及模擬器故障排除 397 13.1 The Structure of a Process Simulator / 過(guò)程模擬器的結(jié)構(gòu) / 398 13.2 Information Required to Complete a Process Simulation: Input Data / 完成過(guò)程模擬所需的信息:輸入數(shù)據(jù) / 401 13.2.1 Selection of Chemical Components / 化學(xué)成分的選擇 / 401 13.2.2 Selection of Physical Property Models / 物性模型的選擇 / 401 13.2.3 Selection and Input of Flowsheet Topology / 流程拓?fù)涞倪x擇和輸入 / 404 13.2.4 Selection of Feed Stream Properties / 進(jìn)料物流特性的選擇 / 404 13.2.5 Selection of Equipment Parameters / 設(shè)備參數(shù)的選擇 / 405 13.2.6 Selection of Output Display Options / 輸出顯示選項(xiàng)的選擇 / 411 13.2.7 Selection of Convergence Criteria and Running a Simulation / 收斂性判定準(zhǔn)則的選擇與仿真 / 411 13.2.8 Common Errors in Using Simulators / 使用模擬器的常見(jiàn)錯(cuò)誤 / 412 13.3 Handling Recycle Streams / 處理再循環(huán)流 / 413 13.4 Choosing Thermodynamic Models / 選擇熱力學(xué)模型 / 415 13.4.1 Pure-Component Properties / 純組分性質(zhì) / 416 13.4.2 Enthalpy / 焓 / 416 13.4.3 Phase Equilibria / 相平衡 / 416 13.4.4 Using Thermodynamic Models / 使用熱力學(xué)模型 / 424 13.5 Case Study: Toluene Hydrodealkylation Process / 案例研究:甲苯加氫脫烷基化工藝 / 426 13.6 Electrolyte Systems Modeling / 電解質(zhì)系統(tǒng)建模 / 428 13.6.1 Fundamentals of Modeling Electrolyte Systems / 電解質(zhì)系統(tǒng)建;A(chǔ) / 429 13.6.2 Steps Needed to Build the Model of an Aqueous Electrolyte System and the Estimation of Parameters / 建立水電解質(zhì)系統(tǒng)模型的步驟和參數(shù)估計(jì) / 435 13.7 Solids Modeling / 實(shí)體模型 / 440 13.7.1 Physical Properties / 物理性質(zhì) / 440 13.7.2 Parameter Requirements for Solids Model / 實(shí)體模型的參數(shù)要求 / 442 附錄13.1 Calculation of Excess Gibbs Energy for Electrolyte Systems 電解質(zhì)系統(tǒng)超額吉布斯能的計(jì)算 / 445 附錄13.2 Steps to Build a Model of a Distillation Column for an Electrolyte System Using a Rate-Based Simulation with a Film Model for Mass Transfer, the Parameters Required at Each Stage, and Possible Sources of These Parameters 使用基于速率的模擬建立電解質(zhì)系統(tǒng)精餾塔模型的步驟,包括傳質(zhì)薄膜模型、每個(gè)階段所需的參數(shù)以及這些參數(shù)的可能來(lái)源 / 447 13.8 Summary / 總結(jié) / 450 References / 參考文獻(xiàn) / 451 Short Answer Questions / 簡(jiǎn)答題 / 454 Problems / 習(xí)題 / 455 第14章 Process Optimization 過(guò)程優(yōu)化 463 14.1 Background Information on Optimization / 優(yōu)化的背景信息 / 463 14.1.1 Common Misconceptions / 常見(jiàn)誤區(qū) / 465 14.1.2 Estimating Problem Difficulty / 評(píng)估問(wèn)題難度 / 467 14.1.3 Top-Down and Bottom-Up Strategies / 自上而下法和自下而上法 / 468 14.1.4 Communication of Optimization Results / 優(yōu)化結(jié)果的討論 / 468 14.2 Strategies / 方法 / 469 14.2.1 Base Case / 基本情況 / 469 14.2.2 Objective Functions / 目標(biāo)函數(shù) / 470 14.2.3 Analysis of the Base Costs / 基礎(chǔ)成本分析 / 471 14.2.4 Identifying and Prioritizing Key Decision Variable / 識(shí)別關(guān)鍵決策變量并確定其優(yōu)先級(jí) / 471 14.3 Topological Optimization / 拓?fù)鋬?yōu)化 / 473 14.3.1 Introduction / 引言 / 473 14.3.2 Elimination of Unwanted Nonhazardous By-Products or Hazardous Waste Streams / 消除不需要的無(wú)害副產(chǎn)品或危險(xiǎn)廢物流 / 473 14.3.3 Elimination and Rearrangement of Equipment / 設(shè)備的淘汰和重新布置 / 475 14.3.4 Alternative Separation Schemes and Reactor Configurations / 可選的分離方案和反應(yīng)器配置 / 477 14.4 Parametric Optimization / 參數(shù)優(yōu)化 / 479 14.4.1 Single-Variable Optimization: A Case Study on T-201, the DME Separation Column / 單變量?jī)?yōu)化:二甲醚分離塔T-201的實(shí)例研究 / 480 14.4.2 Two-Variable Optimization: The Effect of Pressure and Reflux Ratio on T-201, the DME Separation Column / 雙變量?jī)?yōu)化:壓力和回流比對(duì)二甲醚分離塔T-201的影響 / 481 14.4.3 Flowsheet Optimization Using Key Decision Variables / 利用關(guān)鍵決策變量進(jìn)行過(guò)程優(yōu)化 / 484 14.5 Lattice Search, Response Surface, and Mathematical Optimization Techniques / 點(diǎn)陣搜索、響應(yīng)面和數(shù)學(xué)優(yōu)化技術(shù) / 489 14.6 Process Flexibility and the Sensitivity of the Optimum / 過(guò)程靈活性和最佳靈敏度 / 489 14.7 Optimization in Batch Systems / 間歇處理系統(tǒng)中的優(yōu)化 / 490 14.7.1 Problem of Scheduling Equipment / 設(shè)備調(diào)度問(wèn)題 / 490 14.7.2 Problem of Optimum Cycle Time / 最佳周期問(wèn)題 / 495 14.8 Summary / 總結(jié) / 497 References / 參考文獻(xiàn) / 498 Short Answer Questions / 簡(jiǎn)答題 / 498 Problems / 習(xí)題 / 498 第15章 Pinch Technology 夾點(diǎn)技術(shù) 509 15.1 Introduction / 引言 / 509 15.2 Heat Integration and Network Design / 熱集成和網(wǎng)絡(luò)設(shè)計(jì) / 510 15.3 Composite Temperature-Enthalpy Diagram / 復(fù)合溫度-焓圖 / 523 15.4 Composite Enthalpy Curves for Systems without a Pinch / 無(wú)夾點(diǎn)系統(tǒng)的復(fù)合焓曲線 / 524 15.5 Using the Composite Enthalpy Curve to Estimate Heat-Exchanger Surface Area / 用復(fù)合焓曲線估算換熱器表面積 / 525 15.6 Effectiveness Factor (F ) and the Number of Shells / 有效系數(shù)(F)和殼程數(shù) / 529 15.7 Combining Costs to Give the EAOC for the Network / 綜合成本給出網(wǎng)絡(luò)的EAOC / 534 15.8 Other Considerations / 其他注意事項(xiàng) / 536 15.8.1 Materials of Construction and Operating Pressure Issues / 設(shè)備材料和操作壓力 / 536 15.8.2 Problems with Multiple Utilities / 多個(gè)公用設(shè)施 / 539 15.8.3 Handling Streams with Phase Changes / 處理相變流 / 539 15.9 Heat-Exchanger Network Synthesis Analysis and Design (HENSAD) Program / 換熱器網(wǎng)絡(luò)綜合分析與設(shè)計(jì)(HENSAD)程序 / 540 15.10 Mass-Exchange Networks / 質(zhì)量交換網(wǎng)絡(luò) / 541 15.11 Summary / 總結(jié) / 550 References / 參考文獻(xiàn) / 550 Short Answer Questions / 簡(jiǎn)答題 / 551 Problems / 習(xí)題 / 552 第16章 Advanced Topics Using Steady-State Simulators 使用穩(wěn)態(tài)模擬器的前沿主題 561 16.1 Why the Need for Advanced Topics in Steady-State Simulation? / 為什么要在穩(wěn)態(tài)模擬中討論前沿話題 / 562 16.2 User-Added Models / 用戶添加模型 / 562 16.2.1 Unit Operation Models / 單元操作模型 / 563 16.2.2 User Thermodynamic and Transport Models / 用戶熱力學(xué)和傳輸模型 / 564 16.2.3 User Kinetic Models / 用戶動(dòng)力學(xué)模型 / 568 16.3 Solution Strategy for Steady-State Simulations / 穩(wěn)態(tài)模擬的方案策略 / 571 16.3.1 Sequential Modular (SM) / 序貫?zāi)K法(SM)/ 572 16.3.2 Equation-Oriented (EO) / 聯(lián)立方程法(EO)/ 585 16.3.3 Simultaneous Modular (SMod) / 同步模塊化(SMod)/ 586 16.4 Studies with the Steady-State Simulation / 穩(wěn)態(tài)模擬研究 / 589 16.4.1 Sensitivity Studies / 靈敏度研究 / 589 16.4.2 Optimization Studies / 優(yōu)化研究 / 589 16.5 Estimation of Physical Property Parameters / 物性參數(shù)評(píng)估 / 601 16.6 Summary / 總結(jié) / 605 References / 參考文獻(xiàn) / 605 Short Answer Questions / 簡(jiǎn)答題 / 607 Problems / 習(xí)題 / 607 第17章 Using Dynamic Simulators in Process Design 在過(guò)程設(shè)計(jì)中使用動(dòng)態(tài)模擬器 617 17.1 Why Is There a Need for Dynamic Simulation? / 為什么需要?jiǎng)討B(tài)模擬 / 618 17.2 Setting Up a Dynamic Simulation / 建立動(dòng)態(tài)模擬 / 619 17.2.1 Step 1: Topological Change in the Steady-State Simulation / 步驟1:穩(wěn)態(tài)模擬中的拓?fù)渥兓?/ 619 17.2.2 Step 2: Equipment Geometry and Size / 步驟2:設(shè)備幾何形狀和尺寸 / 622 17.2.3 Step 3: Additional Dynamic Data/Dynamic Specification / 步驟3:附加動(dòng)態(tài)數(shù)據(jù)/動(dòng)態(tài)規(guī)范 / 624 17.3 Dynamic Simulation Solution Methods / 動(dòng)態(tài)模擬求解方法 / 633 17.3.1 Initialization / 賦初值 / 634 17.3.2 Solution of the DAE System / DAE系統(tǒng)求解方法 / 634 17.4 Process Control / 過(guò)程控制 / 639 17.5 Summary / 總結(jié) / 647 References / 參考文獻(xiàn) / 647 Short Answer Questions / 簡(jiǎn)答題 / 648 Problems / 習(xí)題 / 649 第18章 Regulation and Control of Chemical Processes with Applications Using Commercial Software 使用商業(yè)軟件對(duì)化工過(guò)程進(jìn)行調(diào)節(jié)和控制 655 18.1 A Simple Regulation Problem / 一個(gè)簡(jiǎn)單的調(diào)節(jié)問(wèn)題 / 656 18.2 The Characteristics of Regulating Valves / 調(diào)節(jié)閥的特性 / 657 18.3 Regulating Flowrates and Pressures / 調(diào)節(jié)流量和壓力 / 660 18.4 The Measurement of Process Variables / 過(guò)程變量的測(cè)量 / 662 18.5 Common Control Strategies Used in Chemical Processes / 化工過(guò)程中常用的控制策略 / 663 18.5.1 Feedback Control and Regulation / 反饋控制和調(diào)節(jié) / 663 18.5.2 Feed-Forward Control and Regulation / 前饋控制和調(diào)節(jié) / 665 18.5.3 Combination Feedback and Feed-Forward Control / 反饋和前饋聯(lián)合控制 / 667 18.5.4 Cascade Regulation / 串級(jí)調(diào)控 / 668 18.5.5 Ratio Control / 比例調(diào)節(jié) / 669 18.5.6 Split-Range Control / 分程控制 / 671 18.6 Exchanging Heat and Work between Process and Utility Streams / 在工藝和公用設(shè)施流之間交換熱量和功 / 674 18.6.1 Increasing the Pressure of a Process Stream and Regulating Its Flowrate / 增加工藝流的壓力并調(diào)節(jié)其流量 / 674 18.6.2 Exchanging Heat between Process Streams and Utilities / 在工藝流和公用設(shè)施之間換熱 / 676 18.6.3 Exchanging Heat between Process Streams / 在工藝流之間換熱 / 679 18.7 Logic Control / 邏輯控制 / 680 18.8 Advanced Process Control / 先進(jìn)過(guò)程控制技術(shù) / 682 18.8.1 Statistical Process Control (SPC) / 統(tǒng)計(jì)過(guò)程控制(SPC)/ 682 18.8.2 Model-Based Control / 基于模型的控制 / 683 18.9 Case Studies / 案例研究 / 683 18.9.1 The Cumene Reactor, R-801 / 異丙苯反應(yīng)器R-801 / 683 18.9.2 A Basic Control System for a Binary Distillation Column / 二元精餾塔的基本控制系統(tǒng) / 685 18.9.3 A More Sophisticated Control System for a Binary Distillation Column / 一種更精密的二元精餾塔控制系統(tǒng) / 687 18.10 Putting It All Together: The Operator Training Simulator (OTS) / 綜合考慮:操作員訓(xùn)練仿真器(OTS)/ 688 18.11 Summary / 總結(jié) / 689 References / 參考文獻(xiàn) / 690 Problems / 習(xí)題 / 690 第4篇 Chemical Equipment Design and Performance Process Equipment Design and Performance 化工設(shè)備和工藝設(shè)備的設(shè)計(jì)與性能 / 695 第19章 Process Fluid Mechanics / 過(guò)程流體力學(xué) 697 19.1 Basic Relationships in Fluid Mechanics / 流體力學(xué)中的基本關(guān)系 / 697 19.1.1 Mass Balance / 物料衡算 / 698 19.1.2 Mechanical Energy Balance / 機(jī)械能衡算 / 700 19.1.3 Force Balance / 力平衡 / 703 19.2 Fluid Flow Equipment / 流體流動(dòng)設(shè)備 / 703 19.2.1 Pipes / 管道 / 703 19.2.2 Valves / 閥門(mén) / 705 19.2.3 Pumps / 泵 / 706 19.2.4 Compressors / 壓縮機(jī) / 707 19.3 Frictional Pipe Flow / 摩擦管流 / 709 19.3.1 Calculating Frictional Losses / 計(jì)算摩擦損失 / 709 19.3.2 Incompressible Flow / 不可壓縮流動(dòng) / 712 19.3.3 Compressible Flow / 可壓縮流動(dòng) / 719 19.3.4 Choked Flow / 壅塞流 / 720 19.4 Other Flow Situations / 其他流動(dòng)情況 / 723 19.4.1 Flow Past Submerged Objects / 流過(guò)水下物體 / 723 19.4.2 Fluidized Beds / 流化床 / 728 19.4.3 Flowrate Measurement / 流量測(cè)量 / 730 19.5 Performance of Fluid Flow Equipment / 流體流動(dòng)設(shè)備的性能 / 736 19.5.1 Base-Case Ratios / 基本方案比率 / 736 19.5.2 Net Positive Suction Head / 汽蝕余量 / 739 19.5.3 Pump and System Curves / 泵與系統(tǒng)曲線 / 743 19.5.4 Compressors / 壓縮機(jī) / 749 19.5.5 Performance of the Feed Section to a Process / 工藝進(jìn)料部分的性能 / 752 References / 參考文獻(xiàn) / 755 Short Answer Questions / 簡(jiǎn)答題 / 756 Problems / 習(xí)題 / 757 第20章 Process Heat Transfer 過(guò)程傳熱 771 20.1 Basic Heat-Exchanger Relationships / 基本換熱器關(guān)系 / 771 20.1.1 Countercurrent Flow / 逆流 / 771 20.1.2 Cocurrent Flow / 并流 / 773 20.1.3 Streams with Phase Changes / 相變流 / 775 20.1.4 Nonlinear Q Versus T Curves / 非線性Q-T曲線 / 776 20.1.5 Overall Heat Transfer Coefficient, U, Varies along the Exchanger / 總傳熱系數(shù)U沿?fù)Q熱器的變化 / 777 20.2 Heat-Exchange Equipment Design and Characteristics / 換熱設(shè)備設(shè)計(jì)及特點(diǎn) / 779 20.2.1 Shell-and-Tube Heat Exchangers / 管殼式換熱器 / 779 20.3 LMTD Correction Factor for Multiple Shell and Tube Passes / 多管程和多殼程的LMTD校正系數(shù) / 789 20.3.1 Background / 背景 / 789 20.3.2 Basic Configuration of a Single-Shell-Pass, Double-Tube-Pass (1-2) Exchanger / 單殼程、雙管程(1-2)換熱器的基本配置 / 790 20.3.3 Multiple Shell-and-Tube-Pass Exchangers / 多管殼式換熱器 / 793 20.3.4 Cross-Flow Exchangers / 錯(cuò)流換熱器 / 797 20.3.5 LMTD Correction and Phase Change / LMTD校正和相變 / 797 20.4 Overall Heat Transfer Coefficients—Resistances in Series / 總傳熱系數(shù)——串聯(lián)熱阻 / 798 20.5 Estimation of Individual Heat Transfer Coefficients and Fouling Resistances / 單項(xiàng)傳熱系數(shù)和污垢阻力的估算 / 800 20.5.1 Heat Transfer Resistances Due to Fouling / 污垢引起的換熱阻力 / 800 20.5.2 Thermal Conductivities of Common Metals and Tube Properties / 常見(jiàn)金屬的熱導(dǎo)率和管材性能 / 800 20.5.3 Correlations for Film Heat Transfer Coefficients / 膜傳熱系數(shù)的關(guān)聯(lián)式 / 803 20.6 Extended Surfaces / 擴(kuò)大換熱面 / 828 20.6.1 Rectangular Fin with Constant Thickness / 等厚矩形翅片 / 829 20.6.2 Fin Efficiency for Other Fin Geometries / 其他形狀翅片的效率 / 830 20.6.3 Total Heat Transfer Surface Effectiveness / 總傳熱表面效率 / 831 20.7 Algorithm and Worked Examples for the Design of Heat Exchangers / 換熱器設(shè)計(jì)的算法與實(shí)例 / 837 20.7.1 Pressure Drop Considerations / 壓降考慮因素 / 837 20.7.2 Design Algorithm / 設(shè)計(jì)算法 / 838 20.8 Performance Problems / 性能問(wèn)題 / 846 20.8.1 What Variables to Specify in Performance Problems / 在性能問(wèn)題中要指定什么變量 / 847 20.8.2 Using Ratios to Determine Heat-Exchanger Performance / 用比值確定換熱器的性能 / 847 20.8.3 Worked Examples for Performance Problems / 性能問(wèn)題的工作示例 / 850 References / 參考文獻(xiàn) / 859 附錄20.A Heat-Exchanger Effectiveness Charts / 換熱器效率圖 / 861 附錄20.B Derivation of Fin Effectiveness for a Rectangular Fin / 矩形翅片的翅片效率推導(dǎo) / 864 Short Answer Questions / 簡(jiǎn)答題 / 866 Problems / 習(xí)題 / 866 第21章 Separation Equipment 分離設(shè)備 875 21.1 Basic Relationships in Separations / 分離中的基本關(guān)系 / 876 21.1.1 Mass Balances / 質(zhì)量衡算 / 876 21.1.2 Energy Balances / 能量衡算 / 877 21.1.3 Equilibrium Relationships / 平衡關(guān)系 / 877 21.1.4 Mass Transfer Relationships / 傳質(zhì)關(guān)系 / 878 21.1.5 Rate Expressions / 速率表達(dá)式 / 882 21.2 Illustrative Diagrams / 示意圖 / 883 21.2.1 TP-xy Diagrams / TP-xy圖 / 883 21.2.2 McCabe-Thiele Diagram / M-T圖 / 888 21.2.3 Dilute Solutions—The Kremser and Colburn Methods / 稀釋溶液——Kremser和Colburn方法 / 905 21.3 Equipment / 設(shè)備 / 911 21.3.1 Drums / 轉(zhuǎn)鼓 / 911 21.3.2 Tray Towers / 板式塔 / 912 21.3.3 Packed Towers / 填料塔 / 926 21.3.4 Tray Tower or Packed Tower? / 板式塔還是填料塔 / 933 21.3.5 Performance of Packed and Tray Towers / 填料塔和板式塔的性能 / 933 Case Study / 案例研究 / 934 21.4 Extraction Equipment / 萃取設(shè)備 / 942 21.4.1 Mixer-Settlers / 混合澄清槽 / 943 21.4.2 Static and Pulsed Columns / 靜態(tài)脈動(dòng)塔 / 943 21.4.3 Agitated Columns / 攪拌塔 / 943 21.4.4 Centrifugal Extractors / 離心萃取器 / 943 21.5 Gas Permeation Membrane Separations / 氣體滲透膜分離 / 947 21.5.1 Equipment / 設(shè)備 / 947 21.5.2 Models for Gas Permeation Membranes / 氣體滲透膜模型 / 949 21.5.3 Practical Issues / 實(shí)際問(wèn)題 / 950 References / 參考文獻(xiàn) / 951 Short Answer Questions / 簡(jiǎn)答題 / 952 Problems / 習(xí)題 / 954 第22章 Reactors 反應(yīng)器 961 22.1 Basic Relationships / 基本關(guān)系 / 962 22.1.1 Kinetics / 動(dòng)力學(xué) / 962 22.1.2 Equilibrium / 平衡 / 964 22.1.3 Additional Mass Transfer Effects / 附加傳質(zhì)效應(yīng) / 965 22.1.4 Mass Balances / 質(zhì)量衡算 / 970 22.1.5 Energy Balances / 能量衡算 / 971 22.1.6 Reactor Models / 反應(yīng)器模型 / 972 22.2 Equipment Design for Nonisothermal Conditions / 非等溫條件下的設(shè)備設(shè)計(jì) / 980 22.2.1 Nonisothermal Continuous Stirred Tank Reactor / 非等溫連續(xù)攪拌釜反應(yīng)器 / 980 22.2.2 Nonisothermal Plug Flow Reactor / 非等溫活塞流反應(yīng)器 / 984 22.2.3 Fluidized Bed Reactor / 流化床反應(yīng)器 / 999 22.3 Performance Problems / 性能問(wèn)題 / 1003 22.3.1 Ratios for Simple Cases / 簡(jiǎn)單案例的比率 / 1003 22.3.2 More Complex Examples / 更復(fù)雜的情況 / 1004 References / 參考文獻(xiàn) / 1007 Short Answer Questions / 簡(jiǎn)答題 / 1007 Problems / 習(xí)題 / 1008 第23章 Other Equipment 其他設(shè)備 1015 23.1 Pressure Vessels / 壓力容器 / 1016 23.1.1 Material Properties / 材料特性 / 1016 23.1.2 Basic Design Equations / 基本設(shè)計(jì)方程 / 1016 23.2 Knockout Drums or Simple Phase Separators / 分液罐或簡(jiǎn)單分相器 / 1024 23.2.1 Vapor-Liquid (V-L) Separation / 氣液(V-L)分離 / 1025 23.2.2 Design of Vertical V-L Separators / 立式氣液分離器的設(shè)計(jì) / 1029 23.2.3 Design of Horizontal V-L Separators / 臥式氣液分離器的設(shè)計(jì) / 1032 23.2.4 Mist Eliminators and Other Internals / 除霧器和其他內(nèi)部構(gòu)件 / 1036 23.2.5 Liquid-Liquid (L-L) Separation / 液液(L-L)分離 / 1044 23.3 Steam Ejectors / 蒸汽噴射器 / 1049 23.3.1 Estimating Air Leaks into Vacuum Systems and the Load for Steam Ejectors / 估算真空系統(tǒng)的空氣泄漏和蒸汽噴射器的負(fù)荷 / 1050 23.3.2 Single-Stage Steam Ejectors / 單級(jí)蒸汽噴射器 / 1051 23.3.3 Multistage Steam Ejectors / 多級(jí)蒸汽噴射器 / 1054 23.3.4 Performance of Steam Ejectors / 蒸汽噴射器的性能 / 1057 References / 參考文獻(xiàn) / 1058 Short Answer Questions / 簡(jiǎn)答題 / 1059 Problems / 習(xí)題 / 1060 第24章 Process Troubleshooting and Debottlenecking 過(guò)程故障排除和瓶頸消除 1065 24.1 Recommended Methodology / 優(yōu)選方法 / 1067 24.1.1 Elements of Problem-Solving Strategies / 解決問(wèn)題策略的原理 / 1067 24.1.2 Application to Troubleshooting Problems / 故障排除問(wèn)題的應(yīng)用 / 1069 24.2 Troubleshooting Individual Units / 單個(gè)單元的故障排除 / 1071 24.2.1 Troubleshooting a Packed-Bed Absorber / 填充床吸收器的故障排除 / 1071 24.2.2 Troubleshooting the Cumene Process Feed Section / 異丙苯工藝進(jìn)料段故障排除 / 1074 24.3 Troubleshooting Multiple Units / 多個(gè)單元的故障排除 / 1076 24.3.1 Troubleshooting Off-Specification Acrylic Acid Product / 不合格丙烯酸產(chǎn)品的故障排除 / 1076 24.3.2 Troubleshooting Steam Release in Cumene Reactor / 異丙苯反應(yīng)器蒸汽釋放的故障排除 / 1078 24.4 A Process Troubleshooting Problem / 過(guò)程故障排除問(wèn)題 / 1081 24.5 Debottlenecking Problems / 消除瓶頸問(wèn)題 / 1085 24.6 Summary / 總結(jié) / 1091 References / 參考文獻(xiàn) / 1091 Problems / 習(xí)題 / 1091 第5篇 The Impact of Chemical Engineering Design on Society 化工設(shè)計(jì)對(duì)社會(huì)的影響 1101 第25章 Ethics and Professionalism 倫理學(xué)和職業(yè)精神 1103 25.1 Ethics / 倫理學(xué) / 1104 25.1.1 Moral Autonomy / 道德自治 / 1105 25.1.2 Rehearsal / 預(yù)演 / 1105 25.1.3 Reflection in Action / 反思行動(dòng) / 1106 25.1.4 Mobile Truth / 多變的真相 / 1107 25.1.5 Nonprofessional Responsibilities / 非職業(yè)責(zé)任 / 1108 25.1.6 Duties and Obligations / 責(zé)任和義務(wù) / 1110 25.1.7 Codes of Ethics / 道德準(zhǔn)則 / 1110 25.1.8 Whistle-Blowing / 披露 / 1115 25.1.9 Ethical Dilemmas / 倫理困境 / 1117 25.1.10 Additional Ethics Heuristics / 其余的道德啟發(fā) / 1118 25.1.11 Other Resources / 其他資源 / 1118 25.2 Professional Registration / 職業(yè)登記注冊(cè) / 1121 25.2.1 Engineer-in-Training / 工程師進(jìn)修 / 1122 25.2.2 Registered Professional Engineer / 注冊(cè)專業(yè)工程師 / 1124 25.3 Legal Liability / 法律責(zé)任 / 1125 25.4 Business Codes of Conduct / 商業(yè)行為準(zhǔn)則 / 1126 25.5 Summary / 總結(jié) / 1127 References / 參考文獻(xiàn) / 1128 Problems / 習(xí)題 / 1129 第26章 Health, Safety, and the Environment 健康、安全和環(huán)境 1131 26.1 Risk Assessment / 風(fēng)險(xiǎn)評(píng)估 / 1131 26.1.1 Accident Statistics / 事故統(tǒng)計(jì) / 1132 26.1.2 Worst-Case Scenarios / 最壞情景分析 / 1133 26.1.3 The Role of the Chemical Engineer / 化學(xué)工程師的作用 / 1134 26.2 Regulations and Agencies / 法規(guī)和機(jī)構(gòu) / 1134 26.2.1 OSHA and NIOSH / OSHA和NIOSH / 1135 26.2.2 Environmental Protection Agency (EPA) / 環(huán)境保護(hù)署(EPA) / 1140 26.2.3 Nongovernmental Organizations / 非政府組織 / 1143 26.3 Fires and Explosions / 火災(zāi)和爆炸 / 1143 26.3.1 Terminology / 專業(yè)術(shù)語(yǔ) / 1143 26.3.2 Pressure-Relief Systems / 減壓系統(tǒng) / 1145 26.4 Process Hazard Analysis / 過(guò)程危害分析 / 1145 26.4.1 HAZOP (Hazard and Operability Study) / HAZOP(危險(xiǎn)與可操作性分析)/ 1146 26.4.2 Dow Fire & Explosion Index and Chemical Exposure Index / 陶氏火災(zāi)爆炸指數(shù)和化學(xué)曝光指數(shù) / 1147 26.5 Chemical Safety and Hazard Investigation Board / 化學(xué)品安全和危險(xiǎn)調(diào)查委員會(huì) / 1153 26.6 Inherently Safe Design / 本質(zhì)安全設(shè)計(jì) / 1153 26.7 Summary / 總結(jié) / 1154 26.8 Glossary / 專業(yè)術(shù)語(yǔ) / 1154 References / 參考文獻(xiàn) / 1156 Problems / 習(xí)題 / 1157 第27章 Green Engineering 綠色工程 1159 27.1 Environmental Regulations / 環(huán)境法規(guī) / 1159 27.2 Environmental Fate of Chemicals / 化學(xué)品的環(huán)境歸宿 / 1160 27.3 Green Chemistry / 綠色化學(xué) / 1163 27.4 Pollution Prevention during Process Design / 工藝設(shè)計(jì)中的污染防治 / 1164 27.5 Analysis of a PFD for Pollution Performance and Environmental Performance / 污染性能和環(huán)境性能的 PFD 分析 / 1166 27.6 An Example of the Economics of Pollution Prevention / 污染防治經(jīng)濟(jì)學(xué)實(shí)例 / 1167 27.7 Life Cycle Analysis / 生命周期分析 / 1168 27.8 Summary / 總結(jié) / 1169 References / 參考文獻(xiàn) / 1170 Problems / 習(xí)題 / 1171 第6篇 Interpersonal and Communication Skills 人際關(guān)系和溝通技巧 1173 第28章 Teamwork 團(tuán)隊(duì)合作 1175 28.1 Groups / 團(tuán)隊(duì) / 1175 28.1.1 Characteristics of Effective Groups / 高效團(tuán)隊(duì)的特征 / 1176 28.1.2 Assessing and Improving the Effectiveness of a Group / 評(píng)估和提高團(tuán)隊(duì)效率 / 1178 28.1.3 Organizational Behaviors and Strategies / 組織行為與策略 / 1180 28.2 Group Evolution / 團(tuán)隊(duì)的發(fā)展歷程 / 1184 28.2.1 Forming / 形成階段 / 1184 28.2.2 Storming / 調(diào)整階段 / 1184 28.2.3 Norming / 規(guī)范化階段 / 1185 28.2.4 Performing / 執(zhí)行階段 / 1186 28.3 Teams and Teamwork / 團(tuán)隊(duì)與團(tuán)隊(duì)合作 / 1186 28.3.1 When Groups Become Teams / 小組變?yōu)閳F(tuán)隊(duì) / 1186 28.3.2 Unique Characteristics of Teams / 團(tuán)隊(duì)的獨(dú)特特征 / 1187 28.4 Misconceptions / 誤區(qū) / 1189 28.4.1 Team Exams / 團(tuán)隊(duì)考核 / 1189 28.4.2 Overreliance on Team Members / 過(guò)度依賴團(tuán)隊(duì)成員 / 1189 28.5 Learning in Teams / 團(tuán)隊(duì)學(xué)習(xí) / 1189 28.6 Other Reading / 其他材料 / 1190 28.7 Summary / 總結(jié) / 1191 References / 參考文獻(xiàn) / 1192 Problems / 習(xí)題 / 1192 第29章 Written and Oral Communication 書(shū)面與口頭交流 1195 29.1 Audience Analysis / 受眾分析 / 1196 29.2 Written Communication / 書(shū)面交流 / 1196 29.2.1 Design Reports / 設(shè)計(jì)報(bào)告 / 1197 29.2.2 Transmittal Letters or Memos / 傳送信件或備忘錄 / 1198 29.2.3 Executive Summaries and Abstracts / 執(zhí)行概述和摘要 / 1198 29.2.4 Other Types of Written Communication / 其他類型的書(shū)面交流 / 1199 29.2.5 Exhibits (Figures and Tables) / 附件(圖片和表格)/ 1200 29.2.6 References / 參考文獻(xiàn) / 1200 29.2.7 Strategies for Writing / 寫(xiě)作方法 / 1201 29.2.8 WVU and Auburn University Guidelines for Written Design Reports / 西弗吉尼亞大學(xué)和奧本大學(xué)書(shū)面設(shè)計(jì)報(bào)告指南 / 1202 29.3 Oral Communication / 口頭交流 / 1209 29.3.1 Formal Oral Presentations / 正式口頭報(bào)告 / 1210 29.3.2 Briefings / 簡(jiǎn)述 / 1211 29.3.3 Visual Aids / 視覺(jué)輔助 / 1211 29.3.4 WVU and Auburn University Oral Presentation Guidelines / 西弗吉尼亞大學(xué)和奧本大學(xué)口頭報(bào)告指南 / 1212 29.4 Software and Author Responsibility / 軟件與作者職責(zé) / 1215 29.4.1 Spell Checkers / 拼寫(xiě)檢查 / 1215 29.4.2 Thesaurus / 同義詞典 / 1215 29.4.3 Grammar Checkers / 語(yǔ)法檢查 / 1215 29.4.4 Graphs / 圖片 / 1216 29.4.5 Tables / 表格 / 1217 29.4.6 Colors and Exotic Features / 色彩與異域特征 / 1217 29.4.7 Raw Output from Process Simulators / 過(guò)程模擬器的初始結(jié)果 / 1217 29.5 Summary / 總結(jié) / 1218 References / 參考文獻(xiàn) / 1218 Problems / 習(xí)題 / 1219 第30章 A Report-Writing Case Study 報(bào)告寫(xiě)作案例研究 1221 30.1 The Assignment Memorandum / 任務(wù)備忘錄 / 1221 30.2 Response Memorandum / 回應(yīng)備忘錄 / 1222 30.3 Visual Aids / 視覺(jué)輔助 / 1224 30.4 Example Reports / 報(bào)告實(shí)例 / 1230 30.4.1 An Example of a Portion of a Student Written Report / 學(xué)生書(shū)面報(bào)告的部分示例 / 1231 30.4.2 An Example of an Improved Student Written Report / 學(xué)生書(shū)面報(bào)告的改進(jìn)示例 / 1232 30.5 Checklist of Common Mistakes and Errors / 常見(jiàn)錯(cuò)誤 / 1243 30.5.1 Common Mistakes for Visual Aids / 視覺(jué)輔助的常見(jiàn)錯(cuò)誤 / 1243 30.5.2 Common Mistakes for Written Text / 書(shū)面文本的常見(jiàn)錯(cuò)誤 / 1244 電子版附錄A Cost Equations and Curves for the CAPCOST Program CAPCOST程序的成本方程和曲線 1247 A.1 Purchased Equipment Costs / 采購(gòu)設(shè)備成本 / 1247 A.2 Pressure Factors / 壓力因素 / 1264 A.3 Material Factors and Bare Module Factors / 材料因素和裸模塊系數(shù) / 1267 電子版附錄B Information for the Preliminary Design of Fifteen Chemical Processes 十五種化工工藝初步設(shè)計(jì)資料 1277 B.1 Dimethyl Ether (DME) Production, Unit 200 / 制備二甲醚(DME)(裝置200)/ 1278 B.2 Ethylbenzene Production, Unit 300 / 制備乙苯(裝置300)/ 1283 B.3 Styrene Production, Unit 400 / 制備苯乙烯(裝置400)/ 1291 B.4 Drying Oil Production, Unit 500 / 制備干性油(裝置500)/ 1299 B.5 Production of Maleic Anhydride from Benzene, Unit 600 / 由苯制備馬來(lái)酸酐(裝置600) / 1305 B.6 Ethylene Oxide Production, Unit 700 / 制備環(huán)氧乙烷(裝置700)/ 1311 B.7 Formalin Production, Unit 800 / 制備福爾馬林(裝置800)/ 1317 B.8 Batch Production of L-Phenylalanine and L-Aspartic Acid, Unit 900 / 批量制備L-苯丙氨酸和 L-天冬氨酸(裝置900)/ 1323 B.9 Acrylic Acid Production via The Catalytic Partial Oxidation of Propylene, Unit 1000 / 丙烯催化部分氧化制備丙烯酸(裝置1000)/ 1329 B.10 Production of Acetone via the Dehydrogenation of Isopropyl Alcohol (IPA), Unit 1100 / 異丙醇(IPA)脫氫制備丙酮(裝置1100)/ 1338 B.11 Production of Heptenes from Propylene and Butenes, Unit 1200 / 丙烯和丁烯制備庚烯(裝置1200)/ 1345 B.12 Design of a Shift Reactor Unit to Convert CO to CO2, Unit 1300 / 設(shè)計(jì)由CO轉(zhuǎn)化為CO2的變換反應(yīng)器(裝置1300)/ 1352 B.13 Design of a Dual-Stage Selexol Unit to Remove CO2 and H2S from Coal-Derived Synthesis Gas, Unit 1400 / 設(shè)計(jì)從煤衍生合成氣中去除CO2和H2S的雙級(jí)Selexol裝置(裝置1400)/ 1356 B.14 Design of a Claus Unit for the Conversion of H2S to Elemental Sulfur, Unit 1500 / 設(shè)計(jì)用于將H2S轉(zhuǎn)化為元素硫的Claus裝置(裝置1500)/ 1363 B.15 Modeling a Downward-Flow, Oxygen-Blown, Entrained-Flow Gasifier, Unit 1600 / 模擬向下流動(dòng)、吹氧、氣流床氣化爐(裝置1600)/ 1371 電子版附錄C Design Projects 設(shè)計(jì)項(xiàng)目 1379 項(xiàng)目1 Increasing the Production of 3-Chloro-1-Propene (Allyl Chloride) in Unit 600 / 提高裝置600的 3-氯-1-丙烯(烯丙基氯)的產(chǎn)量 / 1381 項(xiàng)目2 Design and Optimization of a New 20,000-Metric-Tons-per-Year Facility to Produce Allyl Chloride at La Nueva antina, Mexico 設(shè)計(jì)并優(yōu)化位于墨西哥La Nueva Cantina的年產(chǎn)20000噸烯丙基氯的新設(shè)備 / 1394 項(xiàng)目3 Scale-Down of Phthalic Anhydride Production at TBWS Unit 700 / TBWS 700裝置鄰苯二甲酸酐生產(chǎn)規(guī)?s減 / 1401 項(xiàng)目4 The Design of a New 100,000-Metric-Tons-per-Year Phthalic Anhydride Production Facility / 設(shè)計(jì)新的年產(chǎn)10萬(wàn)噸的鄰苯二甲酸酐生產(chǎn)裝置 / 1412 項(xiàng)目5 Problems at the Cumene Production Facility, Unit 800 / 異丙苯生產(chǎn)設(shè)施的問(wèn)題(裝置800)/ 1417 項(xiàng)目6 Design of a New 100,000-Metric-Tons-per-Year Cumene Production Facility / 設(shè)計(jì)新的年產(chǎn)10萬(wàn)噸的異丙苯生產(chǎn)設(shè)施 / 1430 Index 電子版索引
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